Rumput laut merah
merupakan sumber daya hayati yang terdapat di wilayah pesisir laut dan banyak
ditemui di daerah perairan yang berasosiasi dengan terumbu karang. Selain kadar
gizi yang tinggi, rumput laut banyak diminati karena kandungan agar, alginat,
dan karagenan (Campo et. al., 2009).
Seiring dengan peningkatan kebutuhan bahan baku industri baik untuk food grade, pharmaceutical maupun industrial
grade, perdagangan global telah menunjukkan trend kenaikan yang cukup tinggi terhadap perkembangan pasar
rumput laut. Indonesia merupakan salah satu negara mempunyai peluang besar
dalam memasok kebutuhan bahan baku rumput laut. Pada tahun 2010 kebutuhan
rumput laut Eucheuma sp dunia mencapai 274.100 ton, dimana
Indonesia mempunyai peluang memberikan kontribusi ekspor sebesar 80.000 ton
atau sekitar 29,19% (Badan Pengkajian dan Penerapan Teknologi, 2006 dalam
Cocon, 2011).
Sumba Timur
merupakan salah satu pulau dengan komoditi utama adalah rumput laut. Euchema merupakan rumput laut makroskopik,
tergolong dalam kelas Rhodophyceae dan
telah dibudidayakan di kabupaten ini. Namun Euchema
yang dikembangkan hanya terbatas pada Euchema
cottoni, sedangkan untuk Euchema
spinosum belum dikembangkan. Hal ini disebabkan E.cottoni lebih diminati oleh pasar industri sehingga masyarakat
lebih banyak membudidayakan jenis Euchema
cottoni daripada E. spinosum.
Padahal E. spinosum yang dipanen tiap
tahunnya cukup tinggi namun masih diolah secara tradisional sebagai panganan.
Kajian
tentang kualitas karagenan rumput laut jenis Eucheuma spinosum di daerah ini belum dilakukan,
sehingga data dan informasi yang berhubungan dengan kualitas karagenan tersebut
masih sangat terbatas. Padahal potensi rumput laut Euchema spinosum tidak kalah secara kualitas dan kuantitas dengan Euchema cottoni. Kajian
tentang kualitas karagenan rumput laut jenis Eucheuma spinosum di daerah ini belum dilakukan,
sehingga data dan informasi yang berhubungan dengan kualitas karagenan tersebut
masih sangat terbatas. Padahal potensi rumput laut Euchema spinosum tidak kalah secara kualitas dan kuantitas dengan Euchema cottoni.
Dari hasil penelitian diperoleh konsentrasi NaOH optimum dalam ekstraksi karagenan dari rumput laut Eucheuma spinosum adalah 0,9 N
dengan karakteristik: rendemen 59,07%±3,04; kadar sulfat 10,62%± 0,58; kadar abu 35,00%± 3,30; Viskositas 6,46 cps±
0,13; dan kadar air 11,12%±
0,57. Adapun hasil analisis dengan FTIR
menyatakan adanya gugus fungsi karagenan antara lain: ikatan glikosidik, ester
sulfat, 3,6 anhidro galaktosa, dan galaktosa-4-sulfat.
Gambar spektra FTIR karagenan
Euchema spinosum yang diekstraksi dengan NaOH 0,9N
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